| Configuration: |
Absorbance |
| Collection Mode: |
Rapid Scanning Stopped-Flow |
| Acquisition Time: |
20 seconds (60 scans/second) |
| Description: |
Iain Matheson’s application of Matrix Exponentiation allowed him to quickly write another case for testing the kinetics of an unusually complicated data set acquired by the RSM for a group at the University of Washington. As you see, this
A BCDEF
– a six distinct species, five distinct rates – was achieved with his data.
This is phenomenal. If we thought fitting the five species, four rates was extraordinary, we now are even more astonished. This is unprecedented, unparalleled and truly incredible. There is no fitting algorithm in the world which even pretends to fit such a complicated process.
Secondly, the photometric accuracy and linearity of the RSM must be very high to achieve data which can be fit in this way. The very fact that data can be fit tells us that the linearity must be exceedingly good.
These data have S/N of about 500. Click here for more detailed information. |
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